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- Article name
- Initiation and destruction of chemical reactions in linear chains of smart dimension
- Authors
- VAINSTEIN E. F., , dr_vainshtein@front.ru, N. M. Emanuel Institute of Biochemical Physics of RAS, Moscow, Russia
KRIVOLUTSKAYA I. I., , jasam@jasam.ru, Moscow Aviation Institute (State Technical University), Moscow, Russia
SOLODYSHEVA E. S., , dr_vainshtein@front.ru, Institute of Chemical Physics named after N. N. Semenov of RAS, Moscow, Russia
- Keywords
- chain molecules / smart chains / initiation of new chemical reactions / destruction of available chemical reactions / local rigidity of system / bitterness of system / growth of system flexibility / change of enthalpy / change of entropy / lowering of free energy of Gibbs
- Year
- 2013 Issue 4 Pages 29 - 34
- Code EDN
- Code DOI
- Abstract
- It was theoretically substantiated and experimentally shown, that in field of chains of smart dimension at growth of flexibility of system it is possible initiation of new reactions. If local rigidity of system increased (its flexibility fall) is observed weakening of proceeding of available chemical reactions with their following stopping. System can develop only in side of growth it flexibility. Examples of initiation of new chemical reactions and destruction of available reactions were given.
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